When was the actual moment of Walt becoming Heisenberg and Jimmy becoming Saul?

I know this question has been asked a lot, however 99% of the time it's ironical,

But now I am expecting a serious answer.

My personal takes are: -Jimmy - Chicanery. How he played Chuck into his madness speech. I though that was a real switch. Before that he really cared about Chuck despite everything but after that he no longer cared. All he cared from now on was the money. He became absolutely greedy and went all way with his scams -Walt - Jane's death. He refused to save her life in order to control Jesse. In first season he was apologizing to Krazy 8. After that, again, everything's changed. He became cruel and brutal. He ordered Jesse to kill innocent Gale. He poisoned Brock. He was actually on Todd's side when he (Todd) killed child. He bringed bomb to the hospital. He killed Mike and his men. And most importantly he was doing everything he can to keep Jesse loyal to him